| Martedi 03/05/22 | CHL | Villarreal | 2 - 3 | Liverpool |
|---|---|---|---|---|
| Mercoledi 27/04/22 | CHL | Liverpool | 2 - 0 | Villarreal |
| Martedi 12/04/22 | CHL | Bayern Monaco | 1 - 1 | Villarreal |
| Mercoledi 06/04/22 | CHL | Villarreal | 1 - 0 | Bayern Monaco |
| Mercoledi 16/03/22 | CHL | Juventus | 0 - 3 | Villarreal |
| Martedi 22/02/22 | CHL | Villarreal | 1 - 1 | Juventus |
| Giovedi 09/12/21 | CHL | Atalanta | 2 - 3 | Villarreal |
| Martedi 23/11/21 | CHL | Villarreal | 0 - 2 | Manchester United |
| Martedi 02/11/21 | CHL | Villarreal | 2 - 0 | Young Boys |
| Mercoledi 20/10/21 | CHL | Young Boys | 1 - 4 | Villarreal |
| Mercoledi 29/09/21 | CHL | Manchester United | 2 - 1 | Villarreal |
| Martedi 14/09/21 | CHL | Villarreal | 2 - 2 | Atalanta |
| Martedi 23/08/16 | CHL | Monaco | 1 - 0 | Villarreal |
| Mercoledi 17/08/16 | CHL | Villarreal | 1 - 2 | Monaco |
| Mercoledi 07/12/11 | CHL | Villarreal | 0 - 2 | Napoli |
| Martedi 22/11/11 | CHL | Bayern Monaco | 3 - 1 | Villarreal |
| Mercoledi 02/11/11 | CHL | Villarreal | 0 - 3 | Manchester City |
| Martedi 18/10/11 | CHL | Manchester City | 2 - 1 | Villarreal |
| Martedi 27/09/11 | CHL | Napoli | 2 - 0 | Villarreal |
| Mercoledi 14/09/11 | CHL | Villarreal | 0 - 2 | Bayern Monaco |